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Stereomutation and Asymmetric Induction

FIGURE 4.6 The generation of diastereoisomers depends on the relative rates of reactions. When [Pg.100]

M Goodman, L Levine. Peptide synthesis via active esters. IV. Racemization and ring-opening reactions of optically active oxazolones. JAm Chem Soc 86, 2918, 1964. [Pg.100]

F Weygand, W Steglich, X Boracio de la Lama. On the sterical course of the reaction of oxazol-5-ones with amino-acid esters. Tetrahedron Suppl 8, part 1, 9, 1966. [Pg.100]

J Kovacs, GL Mayers, RH Johnson, RE Cover, UR Ghatak. Racemization of amino acid derivatives. Rates of racemization and peptide bond formation of cysteine esters. J Org Chem 35, 1810, 1970. [Pg.101]

J Kovacs, EM Holleran, KY Hui. Kinetic studies in peptide chemistry. Coupling, racemization, and evaluation of methods useful for shortening coupling time. J Org Chem 45, 1060, 1980. [Pg.101]


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Stereomutation

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