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Spin tensor operators definition

Spin tensor operators play an important role in the second-quantization treatment of electronic systems since they may be used to generate states with definite spin properties. In the remainder... [Pg.42]

The incorporation of spin in second quantization leads to operators with different spin synunetry properties as demonstrated in Section 2.2. Thus, spin-free interactions are represented by operatOTs that are totally symmetric in spin space and thus expressed in terms of orbital excitation operators that affect alpha and beta electrons equally, whereas pure spin interactions are represented by excitation operators that affect alpha and beta electrons differently. For the efficient and transparent manipulation of these operators, we shall apply the standard machinery of group theory. More specifically, we shall adopt the theory of tensor operators for angular momentum in quantum mechanics and develop a useful set of tools for the construction and classification of states and operators with definite spin symmetry properties. [Pg.41]

A vectorial product will be defined below by (5.14), and V as a tensor of first rank is defined by (2.12). Operator L may be defined also in a more general way by the commutation relations of its components. Such a definition is applicable to electron spin s, as well. Therefore, we can write the following commutation relations between components of arbitrary angular momentum j ... [Pg.38]


See other pages where Spin tensor operators definition is mentioned: [Pg.43]    [Pg.606]    [Pg.129]    [Pg.251]    [Pg.99]    [Pg.555]    [Pg.488]   
See also in sourсe #XX -- [ Pg.41 ]




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