Spin-orbit coupling multi-state effects

These quantities are the main players in the theory of nonadiabaticity. In addition to these, can contain spin-orbit couplings. We do not, however, discuss the relativistic effects any fmther, since it is beyond the scope of this book. Interested readers are referred to Ref. [103] This multi-state coupled Schrodinger equation can be transformed into a compact matrix form as shown below... 

The methods of choice must be adequate for manifolds of electronic states that are localized around a lanthanide ion in a solid host. The combination of a solid environment, a heavy element, and 4/, 5d, and other open-shells, demands the consideration of the effects of the solid host, the use of relativistic Hamiltonians up to spin-orbit coupling, the correct treatment of static and dynamic correlation, and handling large manifolds of quasi-degenerate excited states. We decided to use embedded-cluster wavefunction theory-based (EC-WFT) methods, with a two-component relativistic Hamiltonian to be used in two-steps, a multi-configurational variational treatment of static correlation, and a multireference second-order perturbation theory treatment of dynamic correlation. 

Spin-orbit(SO) coupling is an important mechanism that influences the electron spin state [1], In low-dimensional structures Rashba SO interaction comes into play by introducing a potential to destroy the symmetry of space inversion in an arbitrary spatial direction [2-6], Then, based on the properties of Rashba effect, one can realize the controlling and manipulation of the spin in mesoscopic systems by external fields. Recently, Rashba interaction has been applied to some QD systems [6-8]. With the application of Rashba SO coupling to multi-QD structures, some interesting spin-dependent electron transport phenomena arise [7]. In this work, we study the electron transport properties in a three-terminal Aharonov-Bohm (AB) interferometer where the Rashba interaction is taken into account locally to a QD. It is found that Rashba interaction changes the quantum interference in a substantial way. 

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