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Spin-orbit coupling bonding

In fact, for 5d transition-metals relativistic contributions, and in particular spin-orbit coupling, can be of the same order of magnitude as chemical bonding. [Pg.170]

The calculations gave a bond distance of 2.43 A and a bond energy of about 35 kcal/mol, including the effects of spin-orbit coupling. An experimental value of 50 5 kcal/mol was reported in 1974.88... [Pg.272]

Anomalies in the magnitudes of the spin-orbit coupling deduced from optical emission and theoretical studies are also indicative of additional 7r-bonding in the d8 metalloporphyrins. Thus, the spin-orbit coupling which normally increases with atomic number is much smaller for Zn or Cd as compared with Ni or Pd (67). [Pg.94]

See other pages where Spin-orbit coupling bonding is mentioned: [Pg.62]    [Pg.1554]    [Pg.509]    [Pg.339]    [Pg.11]    [Pg.346]    [Pg.347]    [Pg.350]    [Pg.363]    [Pg.363]    [Pg.210]    [Pg.212]    [Pg.122]    [Pg.552]    [Pg.3]    [Pg.121]    [Pg.74]    [Pg.617]    [Pg.80]    [Pg.48]    [Pg.258]    [Pg.71]    [Pg.289]    [Pg.103]    [Pg.125]    [Pg.59]    [Pg.260]    [Pg.276]    [Pg.278]    [Pg.376]    [Pg.202]    [Pg.270]    [Pg.90]    [Pg.14]    [Pg.61]    [Pg.344]    [Pg.170]    [Pg.260]    [Pg.170]    [Pg.260]    [Pg.91]    [Pg.21]    [Pg.126]    [Pg.409]    [Pg.266]    [Pg.364]    [Pg.365]    [Pg.300]   
See also in sourсe #XX -- [ Pg.366 , Pg.386 ]



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