Spectroscopy, organic synthesis

About 1000 papers are published annually on organotin chemistry, and we have been able to include only 5% of these. We have deliberately avoided treating in depth those aspects of the subject that have been thoroughly reviewed recently, and, in particular, we have avoided duplicating the excellent surveys of the use of organotin compounds in organic synthesis (4), of " "Sn Mossbauer spectroscopy (5-9), and of Sn NMR spectroscopy (10-12) that are available. 

Part I deals with chapter involving typical complex organic reactions. Part II deals with various aspects of spectroscopy and the use of this technique in identification of compounds. Miscellaneous reagents used in organic synthesis are discussed in Part III. 

Significant advances in the chemistry of these ring systems over the past 10 years include the first unambiguous detection, and characterization by microwave spectroscopy as 1,2,3-trioxolane, of the primary ozonide from ethene and ozone (cf. Section 4.15.3.2), and the introduction of 1,3,2-dioxathiolane 2,2-dioxides as epoxide equivalents in organic synthesis (cf. Section 4.15.5.3). Advances have also been made in the synthesis and characterization of the chemistry of 1,2,3-trithiolanes and 1,2,3-trithioles. 

Monitoring Solid-Phase Organic Synthesis by FTIR Spectroscopy... 

Li, W. Yan, B. A Direct Comparison of the Mixing Efficiency in Solid-Phase Organic Synthesis By Single Bead IR and Fluorescence Spectroscopy, Tetrahedron Lett. 1997, 38, 6485. 

Svensson A, Fex T, Kihlberg G, Use of 19F NMR spectroscopy to evaluate reactions in solid phase organic synthesis, Tetrahedron Lett., 37(42) 7649-7652, 1996. 

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