Spectroscopic excited state energy from redox potentials

The excited state redox potentials are obtained from the redox potentials of the corresponding ground state and the excited state energy E q q- The redox potential for the excited state to act as an oxidant, E(M /M ), is obtained from the first oxidation potential E0(M -/M) and spectroscopic excited state energy E o,o-... [Pg.125]

The redox potentials of an excited state can be estimated from its spectroscopic energy (0-0 transition, E<>0(M/M )) and the oxidation and reduction potentials of the ground state ... [Pg.166]

As far as the electron transfer processes are concerned (e.g., oxidation of A equation 18), within the approximation described above the redox potentials for the excited-state couple can be calculated from the standard potentials of the ground-state couple and the one-electron potential E°°(V) corresponding to the zero-zero spectroscopic energy (i.e., the value in V) ... [Pg.26]