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Spectroscopic characteristics

The temperature-dependent NMR spectrum of the ion can be analyzed to show that there is a barrier (8.4 kcal/mol) for the ring flip that interchanges the two hydrogens of the methylene group. The C-NMR chemical shift is also compatible with the homoaromatic structure. MO calculations are successful in reproducing the structural and spectroscopic characteristics of the cation and are consistent with a homoaromatic structure. ... [Pg.529]

Pauli s contribution can only be said to explain the closing of the periods if the correct order of filling is assumed, as indeed it was, in the early electronic versions of the periodic table compiled by Bohr and others. But this order of filling was obtained by reference to experimental facts, especially the spectroscopic characteristics of each of the elements (3),... [Pg.43]

The structural features and the spectroscopic characteristics of the thiirene dioxide system (22) are of special theoretical interest since, on the basis of analogy with cyclopropenone (23), it is a possible nonbenzenoid aromatic system with all the physical and chemical implications involved. Aromatic and/or conjugative effects, if any, require transmission through the d-orbitals of the sulfur atom. [Pg.389]

Complexes with pyridine-2,6-diimine ligands, five-coordinate [NiX2(174)] (X = C1, Br) or six-coordinate [Ni(174)2]X2, were usually assumed to have innocent neutral ligands. The X-ray structure and spectroscopic characteristics of [Ni(174)2](PF6) confirm that the complex contains the neutral ligand ([174] ) and a divalent nickel ion.579 The cyclic voltamogram of this complex in CH2C12 shows three reversible one-electron-transfer processes at = 1.19 V, —1.30 V, and — 1.82V (vs. Fc+/Fc), of which the first is a one-electron oxidation, while the other two correspond to two successive one-electron reductions. The spectroscopic data allow one to assign these processes as follows ([174]1 is a one-electron reduced radical form of [174] ) [Nini(174)°2]3+ [NiII(174)02]21 - " [NiI(174)°2]+ = " [NiI(174)°(174)1 ]°. [Pg.296]

There are single- and multiparameter approaches for determining the polarity and separation of contribution of different interactions to the total effect of polarity on spectroscopic characteristics. They are based on different theories of solvatochromic shifts of absorption and fluorescence bands. [Pg.207]

Treating vibrational excitations in lattice systems of adsorbed molecules in terms of bound harmonic oscillators (as presented in Chapter III and also in Appendix 1) provides only a general notion of basic spectroscopic characteristics of an adsorbate, viz. spectral line frequencies and integral intensities. This approach, however, fails to account for line shapes and manipulates spectral lines as shapeless infinitely narrow and infinitely high images described by the Dirac -functions. In simplest cases, the shape of symmetric spectral lines can be characterized by their maximum positions and full width at half maximum (FWHM). These parameters are very sensitive to various perturbations and changes in temperature and can therefore provide additional evidence on the state of an adsorbate and its binding to a surface. [Pg.78]

The rotational mobility of adsorbed molecules is caused by its rotational degree of freedom (resulting from the fact that the molecule is tightly bound to the substrate through the only atom) and by the coupling of molecular vibrations with surface atomic vibrations. The rotational motion intensity is strongly temperature-dependent and affects spectroscopic characteristics. As a result, the rotational mobility of surface hydroxyl groups was reliably detected.200 203... [Pg.159]

Handbook of Organophosphorus Chemistry, Engel, R., Ed., Marcel Dekker, Inc., New York, 1992 — Contributed chapters are concerned with particular types of reactions of organophosphorus compounds, industrial applications of them, and their spectroscopic characteristics. [Pg.22]

These not only exhibit all the structural and spectroscopic characteristics of anomeric amides 2, their reactivity patterns embrace a range of reactions at the amide nitrogen that in many respects parallel those at a saturated carbon.37 46 In addition, they are mutagenic as well as DNA damaging agents that have anticancer capability.37,38,40,46 50 To date nearly a hundred of these have been synthesised in our laboratory while, recently, a range of urea and urethane analogues have also been reported.51 53... [Pg.37]

S.A. Lee, S. Hotta, and F. Nakanishi, Spectroscopic characteristics and intermolecular interactions of thiophene/phenylene co-oligomers in solutions, J. Phys. Chem. A, 104 1827-1833, 2000. [Pg.284]

Each reaction species must have molecular orbitals available and with the correct symmetry to allow bonding. These will be called frontier orbitals composed of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO). In addition to their involvement in bonding between species, these orbitals are of considerable interest in that they are largely responsible for many of the chemical and spectroscopic characteristics of molecules and species and are thus important in analytical procedures and spectroscopic methods of analysis [5-7],... [Pg.71]

To conclude, we have in this chapter combined previously studied subjects of these metal centers to construct corresponding relationships as illustrated Figs. 19 and 20. Using such a range of metal centers, reactivity and structural and general spectroscopic characteristics could be studied in even greater detail. [Pg.115]

Dotted lines show the approximate position of corresponding Spectroscopic characteristics... [Pg.130]


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See also in sourсe #XX -- [ Pg.292 ]




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