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Spectroelectrochemistry formal potential, determination

Spectroelectrochemistry with a thin-layer cell is used to determine the formal potential of a redox system. The absorption curves in Fig. 9.3 were obtained with a thin-layer cell containing a solution of jTclll(dmpe)2Br2]+ (dmpe = l,2-bis(dimethylphosphine)ethane) in 0.5 M Et4NCl04-DMF [4]. On each curve is... [Pg.271]

Spectroelectrochemistry is a rapid and convenient method to study the redox properties of iron proteins. Nernstian behaviour can be readily identified and used to determine the formal reduction potential (Ei/2) and number of electrons ( ) involved in the oxidation/reduction process. Non-Nernstian behaviour can... [Pg.63]

See other pages where Spectroelectrochemistry formal potential, determination is mentioned: [Pg.42]    [Pg.1077]    [Pg.366]    [Pg.1077]    [Pg.4224]    [Pg.147]    [Pg.44]    [Pg.242]    [Pg.563]   
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Formal potential

Potential-determining

Potentials determination

Spectroelectrochemistry

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