Specific determination from

Starch in foods has been analyzed mainly by enzymatic hydrolysis to free the glucose followed by its specific determination. From a nutritional standpoint, starch is present in foods as digestible and RS. RS is that which is not absorbed in the small intestine of healthy humans. From an analytical standpoint, the distinction between digestible and resistant is unclear (Bjbrk, 1996). Nevertheless, RS is virtually insoluble in water and techniques for analyzing total starch in foods have employed either an alkaline (KOH) or organic solvent (DMSO) treatment to successfully disperse the crystalline starch fractions and keep them solubilized. Quantitative analysis of RS in foods has utilized enzymes for their determination (Bjork, 1996). Nevertheless, techniques for analyzing RS in foods need to be established and tested in formal collaborative studies. 

Oleometer. A hydrometer for determining the density of vegetable and sperm oils with a scale from 50° to 0° corresponding to specific gravities from 0.870 to 0.970. See also Fatty Oil Hydrometer above. 

To obtain the monolayer capacity from the isotherm, it is necessary to interpret the (Type II) isotherm in quantitative terms. A number of theories have been advanced for this purpose from time to time, none with complete success. The best known of them, and perhaps the most useful in relation to surface area determination, is that of Brunauer, Emmett and Teller. Though based on a model which is admittedly over-simplified and open to criticism on a number of grounds, the theory leads to an expression—the BET equation —which, when applied with discrimination, has proved remarkably successful in evaluating the specific surface from a Type II isotherm. 

General conclusions determination of specific surface from adsorption isotherms... 

The degree of uncertainty of 10 per cent or more, inseparable from estimates of specific surface from adsorption isotherms, even those of nitrogen, may seem disappointing. In fact, however, attainment of this level of accuracy is a notable achievement in a field where, prior to the development of the BET method, even the order of magnitude of the specific surface of highly disperse solids was in doubt. The adsorption method still provides the only means of determining the specific surface of a mass of non-... 

The concentration of distilled glycerol is easily determined from its specific gravity (15) by the pycnometer method (16) with a precision of 0.02%. Deterrnination of the refractive index also is employed (but not as widely) to measure glycerol concentration to 0.1% (17). 

Detention efficiency. Conversion from the ideal basin sized by detention-time procedures to an actual clarifier requires the inclusion of an efficiency factor to account for the effects of turbulence and nonuniform flow. Efficiencies vaiy greatly, being dependent not only on the relative dimensions of the clarifier and the means of feeding but also on the characteristics of the particles. The cui ve shown in Fig. 18-83 can be used to scale up laboratoiy data in sizing circular clarifiers. The static detention time determined from a test to produce a specific effluent sohds concentration is divided by the efficiency (expressed as a fraction) to determine the nominal detention time, which represents the volume of the clarifier above the settled pulp interface divided by the overflow rate. Different diameter-depth combinations are considered by using the corresponding efficiency factor. In most cases, area may be determined by factors other than the bulksettling rate, such as practical tank-depth limitations. 

The Wenner method is chiefly used to determine the grounding resistance along the pipeline track and the installation positions for cathodic structures. Local limited soil resistivity is most clearly determined from the grounding resistance of an inserted Shephard rod (see Fig. 3-18). Soil stratification can be recognized from the apparent specific soil resistivity, p, by the Wenner method, if a is varied. 

The measures of dimensional variability from Conformability Analysis (CA) (as described in Chapters 2 and 3), specifically the Component Manufacturing Variability Risk, q, is useful in the allocation of tolerances and subsequent analysis of their distributions in probabilistic design. The value is determined from process capability maps for the manufacturing process and knowledge of the component s material and geometry compatibility with the process. In the specific case to the th component bilateral tolerance, it was shown in Chapter 3 that the standard deviation estimates were ... 

A value of Cp = 1.33 would indicate that the distribution of the product characteristics covers 75% of the tolerance. This would be sufficient to assume that the process is capable of producing an adequate proportion to specification. The numbers of failures falling out of specification for various values of Cp and Cp can be determined from Standard Normal Distribution (SND) theory (see an example later for how to determine the failure in parts-per-million or ppm). For example, at Cp = 1.33, the expected number of failures is 64 ppm in total. 

Also, in cases where the dimensions of a regular particle vary throughout a bed of such particles or are not known, but where the fractional free volume and specific surface can be measured or calculated, the shape factor can be calculated and the equivalent diameter of the regular particle determined from Figure 2. 

Constants C and K can be determined from several measurements of filtrate volumes taken at different time intervals. There are some doubts as to the actual constancy of C and K during constant pressure filtration. Constants C and K depend on r (specific volumetric cake resistance), which, in turn, depends on the pressure drop across the cake. This AP causes some changes in the cake, especially during the initial stages of filtration. When the cake is very thin, the main portion of the total pressure drop is exerted on the filter medium. As the cake becomes thicker, the pressure drop through the cake increases rapidly but then levels off to a constant value. Isobaric filtration shows insignificant deviation from the expressions developed. For approximate calculations, it is possible to neglect the resistance of the filter plate, provided the cake is not too thin. Then the filter plate resistance, Rf, is equal to zero, C = 0, and r = 0. Hence, a simplified equation is = Kr. 

The duly for heating free water may be determined from die following equation by assuming a water specific heat of J. 0 Btu/lb- F. 

Initial shock-wave overpressure can be determined from a one-dimensional technique. It consists of using conservation equations for discontinuities through the shock and isentropic flow equations through the rarefaction waves, then matching pressure and flow velocity at the contact surface. This procedure is outlined in Liepmatm and Roshko (1967) for the case of a bursting membrane contained in a shock tube. From this analysis, the initial overpressure at the shock front can be calculated with Eq. (6.3.22). This pressure is not only coupled to the pressure in the sphere, but is also related to the speed of sound and the ratio of specific heats. 

Finally, a fourth motivation for exploring gas solubilities in ILs is that they can act as probes of the molecular interactions with the ILs. Information can be discerned on the importance of specific chemical interactions such as hydrogen bonding, as well as dipole-dipole, dipole-induced dipole, and dispersion forces. Of course, this information can be determined from the solubility of a series of carefully chosen liquids, as well. FLowever, gases tend to be of the smallest size, and therefore the simplest molecules with which to probe molecular interactions. 

Data from ref [31] the elastic constants were measured by the pulse-echo technique j3 was determined from low-temperature specific heat data. 

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