Solid heterometallic compounds

Kornienko, A., Banerjee, S., Kumar, G.A., Riman, R.E., Emge, T.J., and Brennan, J.G. (2005) Heterometallic chalcogenido clusters containing lanthanides and main group metals emissive precursors to ternary solid-state compounds. /. Am. Chem. Soc., 127,14008-14014. 

A further few ionic compounds based on unsupported heterometallic interactions between metal centers from the anion and the cation were reported only recently [604—606]. Thus, treatment of [Ag(Tab)2](PF6) with K[Au(CN)2] generated the complex [ (Tab)2Ag Au(CN)2 ]2 446 [605]. In the solid state [Ag(Tab)2]+ cations and [Au(CN)2] anions are held together via ionic interactions [Au-Ag 2.9598(7)/2.9185... 

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