Sodium hexachlororhodate

If the thioarsine ligand (64) is allowed to react with aqueous rhodium trichloride then the tetrachlororhodate salt is formed. A similar reaction gives rise to the tetrabromo complex (equation 180). The tetraiodo complex can be prepared by addition of Lil to sodium hexachlororhodate(III) and the ligand (equation 181).916... 

Nitrosylpentaamminecobalt(II) chloride, synthesis 49 cts-Bromoamminebis (ethylenediamine) cobal t (111) bromide, CIS- and trans-aquoamminebis(ethylenediamine)cobalt(IIl) bromide, and cis- and triphenylphosphine)rhodium and chloro-carbonylbis(triphenylarsine)rhodium, synthesis 56 Sodium hexachlororhodate(III) 2-hydrate and potassium hexachlororhodate(III) 1-hydrate, synthesis 57 Ammonium hexachloroiridate(IV), synthesis 58 Resolution of the tris(l,10-phenanthroline)nickel(II) ion, synthesis 59... 

SODIUM HEXACHLORORHODATE(m) 2-HYDRATE AND POTASSIUM HEXACHLORORHODATE(m) 1-HYDRATE... 

Potassium hexachlororhodate(III) 1-hydrate may be obtained by chlorination of a mixture of powdered rhodium and potassium chloride, followed by crystallization from the reaction mixture solution in the presence of excess potassium chloride. It may also be prepared by reaction of sodium hexachlororhodate(III) solution with concentrated potassium chloride solution, followed by evaporation to incipient crystallization. Both of these methods are reported to yield potassium pentachloroaquorhodate(III) if potassium chloride is not present in excess. - Anhydrous potassium hexachlororhodate(III) is obtained by heating potassium hexachlororhodate(III) 1-hydrate at 100 to 120°. ... 

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