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Singlet oxygen silyl enol ether reaction

From singlet oxygen reaction with silyl enol ethers. 779... [Pg.775]

From singlet oxygen reaction with silyl enol ethers When a carbon tetrachloride solution of 1-methoxy-l-trimethylsiloxy-l-alkene in the presence of tetraphenylporphyrin and bubbling oxygen is irradiated with a 400-W Na lamp, a-trimethylsilyl peroxyesters were obtained in good yield (equation 11) . ... [Pg.779]

While the reaction of singlet oxygen with silyl enol ethers was governed by competing prototropic and silatropic ene processes (see Section 2.3.2.1.3.ii), the interaction with dienol ethers displays a different mode of reactivity. Singlet oxygen generated from triphenyl phosphite ozonide at low temperature... [Pg.177]

The trimethylsilyl group of enol silyl ethers can participate in ene reactions with singlet oxygen (60,61). [Pg.172]


See other pages where Singlet oxygen silyl enol ether reaction is mentioned: [Pg.594]    [Pg.324]    [Pg.324]    [Pg.357]    [Pg.165]    [Pg.169]    [Pg.165]    [Pg.169]    [Pg.174]    [Pg.305]    [Pg.1068]    [Pg.1068]    [Pg.165]    [Pg.169]    [Pg.1068]    [Pg.206]    [Pg.174]    [Pg.177]   
See also in sourсe #XX -- [ Pg.779 ]




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Enol oxygenation

Enolate oxygenation

Enolates silylation

Enolates, silyl reactions

Oxygen enolate

Oxygen enolates

Oxygen, singlet enol ethers

Oxygenation singlet oxygen

Silyl enol ethers

Silyl enol ethers reaction

Silyl enolate

Silyl enolates

Silyl ethers reactions

Silylation reactions

Singlet oxygen

Singlet oxygen reactions

Singlet oxygenation

Singlet reaction

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