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Single electron transfer reaction of perfluoroalkyl halides

4 Single electron transfer reaction of perfluoroalkyl halides [Pg.121]

The SET reactions can be initiated by organic anions such as carbanions and heteroatom anions, reducing organic reagents such as tetrakis(N,N-dimethylamino)ethene, low valent metal, and electrochemical reduction. Irradiation by UV light is sometimes useful for the acceleration of SET reactions, but it is not necessarily required when good electron donors, for instance thiolates instead of thiols, are used. The chain reactions of, in particular, less reactive perfluoroalkyl bromides are inhibited by species such as nitrobenzene, para-dinitrobenzene, and hydroquinone [3,6]. The reactivity order of perfluoroalkyl hahdes [Pg.122]




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Electron single

Halide transfer

Halides, electron transfer

Of single reactions

Perfluoroalkyl

Perfluoroalkyl halides

Perfluoroalkylation

Reaction single reactions

Single electron transfer

Single electron transfer reactions

Single reactions

Transfer of electron

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