Single Component Calibration

Danzer K, Currie LA (1998) IUPAC, Analytical Chemistry Division, Commission on General Aspects of Analytical Chemistry Guidelines for calibration in analytical chemistry part 1. Fundamentals and single component calibration (Recommendations 1998), Pure Appl Chem 70 993... 

Fig. 6.22. Structure of a RBF net with one hidden layer with bias neuron and one output unit as used for single component calibration (according to Fischbacher et al. [1997] Jagemann [1998])...

I. Fundamentals and single component calibration (IUPAC Recommendations 1998), Comm. Gen. Asp. Anal. Chem., 70 (1998), 993-1014. 

International Union of Pure and Applied Chemistry, Guidelines for Calibration in Analytical Chemistry. Part 1. Fundamentals and Single Component Calibration, 1998. 

K. Danzer and L. A. Currie, Guidelines for calibration in analytical chemistry. Part 1 Fundamentals and single component calibration. Pure Appl. Chem., 1998, 70, 993 1014. 

O-SCD is selective for sulfiir, to which it responds quantitatively, irrespective of the compound. Other products of combustion do not chemiluminesce with ozone. O-SCD shows high sensitivity (<3 ngS), equimolar and linear response (>4 orders), high selectivity (>10 ), and absence of quenching (reliable quantitation in ppm to 40% range) only a single component calibration blend is required. Samples up to 500 mg may be handled. GC-SCD is suitable for odorant analysis. In the case of RCD it is the NO, produced from oxidation of the sulfur compound by NO2, which is reacted with O3 to form the chemiluminescent NO the RCD responds to oxidisable species and not selectively to sulfur. Simultaneous nitrogen/sulfur chemiluminescence (GC-SCD/CLND) is possible [556]. The use of SCDs was reviewed [557]. 

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