Silver-substituted diazomethyl compounds

Synthesis and Reactivity of Silver-Substituted Diazomethyl Compounds... 

Diazomethyl compounds are an extremely useful class of molecules for synthetic organic chemistry. Silver-substituted diazomethyl compounds have further increased the scope of these reagents. The thermally unstable argentodiazoesters are synthesized in situ by treating the corresponding diazoester with silver oxide. The resulting... 

Silver(diazomethyl)phosphoryl compounds may also be synthesized by treatment of the corresponding diazophosphoryl compound with silver oxide. The thermally stable phosphoryl derivatives undergo electrophilic substitution with alkyl iodides73 but, unlike the carbonyl-substituted derivatives, also undergo electrophilic diazoalkane substitution with a variety of Hiickel aromatic salts (Scheme 1.31).74—79... 

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See also in sourсe #XX -- [ ]

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