Silane, organic derivatives

Reactions of Vinyl-Substituted Silanes with Vinyl-Snbstitnted Hetero(N,S3)organic Derivatives... 

Allied to these anions are -Os ozonide, -I3 triiodide, - Nz azide, and -0 0- peroxide (see above). -S2— is disulphide, but in this series it has become the practice to name t he chain compounds H8 [S]a SH as sulphanes (00=1, trisulphane 00=2, tetrasulphane etc,), especially for organic derivatives, by analogy with the alkanes it has analogy, too, with the silane nomenclature and is now accepted by ITJPAC. ... 

This method of silanation, which uses organic solvent without the addition of water, is suitable for highly reactive silane derivatives, such as chlorosilanes, aminosilanes, and methoxysilanes. This procedure will not work for ethoxysilanes, as these compounds are not reactive enough without prior hydrolysis to create the silanol. This method is convenient to use for silica particle modification and for the functionalization of metallic nanoparticles having the requisite—OH groups present (see Chapter 14, Section 5). 

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