Significant Recent Examples of Electropolymerized Pyrrole and Thiophene-Substituted Porphyrins

Significant Recent Examples of Electropolymerized Pyrrole-and Thiophene-Substituted Porphyrins 

In the last decade, Mn(III) porphyrin-modified polypyrrole films were reported and used to mimic electrochemically and advantageously the functioning of cytochrome P450, an enzyme of the monooxygenase type . Indeed, various families of compounds, namely Mn(III) porphyrin derivatives such as 8,9,10,12 

More recently, polythiophenes, some of which were substituted with porphyrin moieties as light harvesters, had been investigated for their performances in photovoltaic devices. In an original work, Shinkai et al. succeeded in the electropolymerization of a Ce(III) triple decker porphyrin complex bearing bithienyl substituents at an ITO electrode surface.  

Significant Examples of Electropolymerized Pyrroie-Substituted Phthalocyanines 

Significant Exampies of Eiectropolymerized Pyrrole-or Thiophene-Substituted Schiff Bases and Related Derivatives 

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