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Sigmatropic rearrangements carbon shifts

This is called (1, 3) shift because the original o bond attached at carbon 1 has been broken and it has attached itself at the carbon 3. But in a petadiene of the type given below (1,5) sigmatropic rearrangement can take place. [Pg.73]

Sandmeyer reaction, 306 Sandwich compoimds, 275 Sawhorse projections, 7 Saytzev elimination, 249, 256 Schiff bases, 221 Schmidt rearrangement, 122 Selectivity, 156, 169, 326 a, 362 a, 370 372 aj,385 a bonds, 6 o complexes, 41,131 Sigmatropic rearrangements, 352-357 antarafacial, 353 carbon shifts, 354 hydrogen shifts, 352 orbital symmetry in, 352 photochemical, 354 suprafadal, 353 thermal, 353... [Pg.213]

This reaction does not proceed via a Whitmore 1,2-shift, but instead is a concerted pericyclic [3,3] sigmatropic rearrangement that results in a cyclic ketone, which after tautomerisation, gives the phenol. Furthermore, in this reaction a C-0 bond is broken, rather than made, and a C-C bond is formed thus, it could have been considered under carbon/carbon rearrangements. [Pg.322]


See other pages where Sigmatropic rearrangements carbon shifts is mentioned: [Pg.1454]    [Pg.1185]    [Pg.209]    [Pg.597]    [Pg.759]    [Pg.526]    [Pg.166]    [Pg.1143]    [Pg.166]    [Pg.1154]    [Pg.4]    [Pg.74]    [Pg.515]    [Pg.518]    [Pg.515]    [Pg.518]    [Pg.494]    [Pg.134]    [Pg.111]    [Pg.7]    [Pg.736]    [Pg.187]    [Pg.187]    [Pg.261]    [Pg.355]    [Pg.4]    [Pg.28]    [Pg.707]    [Pg.830]    [Pg.1001]    [Pg.1003]    [Pg.1009]    [Pg.515]    [Pg.518]    [Pg.154]    [Pg.1677]    [Pg.597]    [Pg.204]    [Pg.950]    [Pg.1201]    [Pg.759]    [Pg.166]    [Pg.707]   
See also in sourсe #XX -- [ Pg.354 ]

See also in sourсe #XX -- [ Pg.354 ]

See also in sourсe #XX -- [ Pg.5 , Pg.271 , Pg.272 ]




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1,2-Shifts sigmatropic rearrangements

Carbon rearrangement

Rearrangements 1,2-shifts

Sigmatropic -rearrangements rearrangement

Sigmatropic shifts 1.3] -carbon

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