Shultz-Flory plot

However, UCST and LCST values of a given polymer/solvent pair depend strongly on the molar mass of the polymer. In the case of monodisperse polymers, this dependency can be described in good approximation by the so-called Shultz-Flory plot (see Refs. 6 and 8) ... [Pg.2207]

The extrapolation point to the vertical axis in the limit of n oo gives the theta temperature, while the slope of the curve gives the Shultz-Flory constant Such an analysis is called a Shultz-Flory plot. [Pg.78]

As opposed to Shultz-Flory s plot (Equation 3.1-246) with 7 c (i.c. phase boundary at the critical temperature) for several polymer fractions, the plot... [Pg.327]

Fig. 122.—A plot of the reciprocal of the critical temperature against the molecular size function occurring in Eq. (7) for polystyrene fractions in cyclohexane (O) and for polyisobutylene fractions in diisobutyl ketone (0). (Shultz and Flory. )...

$Fig. 122.—A plot of the reciprocal of the critical temperature against the molecular size function occurring in Eq. (7) for polystyrene fractions in cyclohexane (O) and for polyisobutylene fractions in diisobutyl ketone (0). (Shultz and Flory. )...$

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