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Short-Range Order of Dissolved Species

The short-range order of dissolved cations like Fe +, Co +, Ni +, Mn +, Cr +, and Fe + have been examined with EXAFS but also with x-ray diffraction (XRD) and neutron scattering. The counterions were CF, NO3, and ClOl. Although these cations did not [Pg.11]

In situ EXAFS of dissolved Ag ions in front of a dissolving Ag electrode (a) with and without Ag dissolution, inset fc -weighted x(k) and (b) T(x(k)k ) to distance space showing first coordination shell. Inset Fourier backtransform of truncated first coordination shell and comparison with simulation (dashed) with R = 0.23 nm, N = 2.15, a = 0.0103. (From Lutzenkirchen-Hecht, D. et al.. Corn ScL, 40,1037,1998.) [Pg.12]


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