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Shielding tensors diamagnetic contribution

A common origin paramagnetic contribution can subsequently be obtained as the difference between the LORG total shielding tensor and the diamagnetic contribution from eq.(29), i.e. [Pg.203]

The diamagnetic contribution to the shielding tensors can be defined as the derivative of this Hamiltonian with respect to the magnetic moment Uk=YkIk of nucleus K and the external magnetic field... [Pg.371]

The diamagnetic contribution to the shielding tensor consists of two terms... [Pg.375]

Direct relationships between the P NMR parameters and structure are complicated by the fact that the chemical shifts are determined in phosphorus compounds predominantly by the paramagnetic rather than the diamagnetic contribution to the shielding tensor. This paramagnetic term is not necessarily directly related to the bonding electron... [Pg.438]

This nuclear Diamagnetic Shielding operator contributes to the NMR shielding tensor. [Pg.332]

In the spirit of the Geertsen method. Smith et al. [26] proposed a sum-over-state expression for the diamagnetic contribution to the nuclear magnetic shielding tensor. They used the commutator... [Pg.111]

Table 5.1 Operators and factors of the diamagnetic contributions to the magne-tizability, nuclear magnetic shielding and reduced indirect nuclear spin-spin coupling tensors... Table 5.1 Operators and factors of the diamagnetic contributions to the magne-tizability, nuclear magnetic shielding and reduced indirect nuclear spin-spin coupling tensors...
Exercise 5.10 The expressions for the diamagnetic and paramagnetic contributions to the magnetizability and nuclear magnetic shielding tensor in equations (5.44) and (5.85) depend... [Pg.121]

See other pages where Shielding tensors diamagnetic contribution is mentioned: [Pg.197]    [Pg.198]    [Pg.199]    [Pg.372]    [Pg.472]    [Pg.79]    [Pg.3]    [Pg.79]    [Pg.104]    [Pg.289]    [Pg.291]    [Pg.300]    [Pg.108]    [Pg.108]    [Pg.62]    [Pg.14]    [Pg.16]    [Pg.287]    [Pg.287]    [Pg.296]    [Pg.34]    [Pg.78]    [Pg.108]    [Pg.337]    [Pg.331]    [Pg.66]    [Pg.462]    [Pg.62]    [Pg.21]    [Pg.314]    [Pg.29]    [Pg.252]    [Pg.108]    [Pg.802]    [Pg.296]    [Pg.114]    [Pg.116]    [Pg.118]    [Pg.118]    [Pg.123]   
See also in sourсe #XX -- [ Pg.289 , Pg.291 ]



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Diamagnetic

Diamagnetic contribution

Diamagnetic shielding

Diamagnetic shielding contribution

Diamagnetics

Diamagnetism

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Shielding diamagnetism

Tensor shielding

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