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Shape resonances orbital picture

The fixation of parameters d (those of the shape of the hybridization tetrahedron) can be considered as FO fixed orbitals) picture [93]. In this case only the resonance energy is the orientation dependent contribution. The angular dependence of the energy (bending) can be described by introducing small rotation vectors S(prm which after applying them to vectors CRmLm (distorted) coordination tetrahedron. The final result of... [Pg.222]

Figure 15 One-dimensional picture of a core-excited shape resonance and a core-excited Feshbach resonance. The two anion states differ in whether the electron attaches to an orbital associated with AB or with CD. Reprinted from Ref. 83 copyright 2008 Elsevier. Figure 15 One-dimensional picture of a core-excited shape resonance and a core-excited Feshbach resonance. The two anion states differ in whether the electron attaches to an orbital associated with AB or with CD. Reprinted from Ref. 83 copyright 2008 Elsevier.
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See also in sourсe #XX -- [ Pg.266 ]



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