Sensitizers sulfato

None of the complexes discussed above react with molecular oxygen to form sulfato products (though most are air sensitive) and in general they exhibit little SO2 lability. In this light the geometry of the complex Ni(f-BuNC)j(S02) XXXI), which exhibits rj -... 

SULFATO CALCICO (Spanish) (7778-18-9) Reacts violently with reducing agents, acrolein, alcohols, chlorine trifluoride, diazomethane, ethers, fluorine, hydrazine, hy-drazinium perchlorate, hydrogen peroxide, finely divided aluminum or magnesium, peroxy-furoic acid, red phosphorus, sodium acetylide. Sensitizes most organic azides that are unstable shock and heat explosives. May form explosive materials with l,3-di(5-tetrazoyl)tri-azene. Incompatible with glycidol, isopropyl chlorocarbonate, nitrosyl perchlorate, sodium borohydride. 

Reduction. Zinc, H2SO4 and reduce Nb sulfato complexes to diamagnetic KNb(S04)2-4H20, sensitive to O2. This solution, stable under CO2, reduces NO to NH3, and also reduces U, V, Mo, Fe , Cu and Tl . Furthermore it is a source of Nb 0Nb (P04)2 6H20 etc. 

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