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Semibridging ligands

A rotated structure that yields a bridging or semibridging CO ligand and... [Pg.29]

Weakly semibridging carbonyls, such as those in Os4(CO),4, are nearly linear but show some distortion toward the second metal. Of course it is not always clear whether departures from linearity arise from interaction with the metal or because of packing forces in the crystalline solid. All CO ligands are fully nonbridging in the puckered 034(00),, described as a metal carbonyl analogue of cyclobutane. 5 The dark red crystals of Os4(CO) j possess nearly planar OS4 units with only terminal CO ligands. [Pg.844]

The product (40% yield) contains semibridging carbonyl ligands ... [Pg.89]

See other pages where Semibridging ligands is mentioned: [Pg.104]    [Pg.104]    [Pg.176]    [Pg.268]    [Pg.298]    [Pg.77]    [Pg.330]    [Pg.180]    [Pg.200]    [Pg.210]    [Pg.280]    [Pg.59]    [Pg.64]    [Pg.78]    [Pg.80]    [Pg.139]    [Pg.46]    [Pg.307]    [Pg.310]    [Pg.2]    [Pg.28]    [Pg.349]    [Pg.349]    [Pg.352]    [Pg.368]    [Pg.211]    [Pg.181]    [Pg.250]    [Pg.251]    [Pg.257]    [Pg.57]    [Pg.269]    [Pg.47]    [Pg.47]    [Pg.1146]    [Pg.2955]    [Pg.3776]    [Pg.3779]    [Pg.4040]    [Pg.326]    [Pg.98]    [Pg.330]    [Pg.321]    [Pg.844]   
See also in sourсe #XX -- [ Pg.636 ]

See also in sourсe #XX -- [ Pg.636 ]

See also in sourсe #XX -- [ Pg.636 ]

See also in sourсe #XX -- [ Pg.636 ]

See also in sourсe #XX -- [ Pg.636 ]



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Carbonyl ligand semibridging

Semibridging

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