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Semi-rigid rotor

The molecule exhibits complex rotational and rotation-vibrational spectra in the microwave and millimetre wave regions due to the internal rotation of the N2 and CO subunits. Since the behaviour of the complex considerably deviates from that of a semi-rigid rotor, the rotational energy levels are treated for different K stacks separately according to... [Pg.242]

The term "exact" means that the reported results are based on a rigorous derivation and are strictly valid within the approximations of the harmonic oscillator and the semi-rigid rotor. [Pg.9]

The T configuration of N2 Ar and the linear geometry of HCl Ar represent orientations at the minima of their potential surfaces. In the last column at the top we have free rotor (112)2 and at the bottom semi-rigid (hydrogen bonded) (HF)2 The molecule (02)2 is a hindered rotor complex.Below we discuss energy transfer processes of a number of the complexes shown in Fig. 3. [Pg.81]

See other pages where Semi-rigid rotor is mentioned: [Pg.303]    [Pg.304]    [Pg.227]    [Pg.223]    [Pg.303]    [Pg.304]    [Pg.227]    [Pg.223]    [Pg.439]    [Pg.280]    [Pg.280]    [Pg.421]    [Pg.358]    [Pg.359]    [Pg.788]    [Pg.324]    [Pg.184]    [Pg.79]    [Pg.193]   
See also in sourсe #XX -- [ Pg.4 , Pg.223 ]



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Centrifugal distortion the semi-rigid rotor

Rigid rotor

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