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Self-sorting system

With proper design and implementation, however, it is possible to construct a self-sorting system whose behavior is different from its components [33c]. For example, consider the simple system comprising two hosts (A and B) and two guests (M and N) that can form four possible host-guest complexes (AM, AN, BM, and BN). We fix the total concentrations of hosts A and B ([A J and [B J) at 1 mM and choose the four equilibrium constants such that host A (KT-fold) and host B (10-fold) both prefer guest M (Scheme 4.7). The various mole fraction definitions (Scheme 4.7c) are used to construct a plot (Scheme 4.7d) of the composition of the mixture as a function of total guest concentration ([M J = [Nj J). When [AjJ = [Bj J > = [Nj j], complexes AM and BN dominate because... [Pg.125]

Development of Complex Self-Sorting Systems at the University of Maryland... [Pg.126]

This section describes the development of self-sorting systems that has occurred in our laboratory over the past 5 years [34],... [Pg.126]

The CB[n] Family of Macrocycles are Prime Components for the Construction of Self-Sorting Systems... [Pg.130]

SELECTED EXAMPLES OF SELF-SORTING SYSTEMS FROM OTHER LABORATORIES 135... [Pg.135]

Selected Examples of Self-Sorting Systems from Other Laboratories... [Pg.135]

Self-Sorting Systems Based on Porphyrin Coordination Chemistry... [Pg.135]

Most recently, several groups have been pushing self-sorting systems into new areas by introducing new concepts derived from either biological... [Pg.148]

See other pages where Self-sorting system is mentioned: [Pg.118]    [Pg.120]    [Pg.120]    [Pg.122]    [Pg.124]    [Pg.124]    [Pg.125]    [Pg.125]    [Pg.126]    [Pg.126]    [Pg.127]    [Pg.127]    [Pg.129]    [Pg.129]    [Pg.130]    [Pg.130]    [Pg.130]    [Pg.131]    [Pg.132]    [Pg.132]    [Pg.133]    [Pg.133]    [Pg.134]    [Pg.135]    [Pg.136]    [Pg.137]    [Pg.138]    [Pg.140]    [Pg.140]    [Pg.140]    [Pg.142]    [Pg.143]    [Pg.144]    [Pg.144]    [Pg.146]    [Pg.148]    [Pg.148]    [Pg.149]    [Pg.150]    [Pg.152]    [Pg.152]   
See also in sourсe #XX -- [ Pg.798 , Pg.800 ]



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Preparation of Complex Self-Sorting Systems

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