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Selenophenyl glycosides

Thiophenyl Glycosides and Selenophenyl Glycosides (Different Donors, Common Activator) Changing from thioethyl glycosides to selenophenyl glycosides... [Pg.222]

Fig. 4 Four levels of anomeric reactivity by using thioethyl and selenophenyl glycosides... Fig. 4 Four levels of anomeric reactivity by using thioethyl and selenophenyl glycosides...
W. R. Roush, D. P. Sebesta, and R. A. James, Stereoselective synthesis of 2-deoxy-p-glycosides from glycal precursors. 2. Stereochemistry of glycosidation reactions of 2-thiophenyl- and 2-selenophenyl-a-D-g/uco-pyranosyl donors, Tetrahedron, 53 (1997) 8837-8852. [Pg.204]

On the other hand, the reactivity-tuned coupling of selenophenyl donor 92 and thioethyl glycoside 93, mediated by NIS/TMSOTf, proceeded smoothly to give the disaccharide 94 as a single anomer in 77% yield. The Aloe group was selected to control the a-selectivity of the glycosylation reaction. [Pg.62]


See other pages where Selenophenyl glycosides is mentioned: [Pg.216]    [Pg.222]    [Pg.234]    [Pg.120]    [Pg.101]    [Pg.376]    [Pg.31]    [Pg.47]    [Pg.58]    [Pg.376]    [Pg.216]    [Pg.222]    [Pg.234]    [Pg.120]    [Pg.101]    [Pg.376]    [Pg.31]    [Pg.47]    [Pg.58]    [Pg.376]    [Pg.242]    [Pg.111]    [Pg.165]    [Pg.92]    [Pg.146]    [Pg.390]    [Pg.319]    [Pg.103]    [Pg.103]    [Pg.1156]   
See also in sourсe #XX -- [ Pg.222 ]




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