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Selenocyanates linkage isomers

Selenium, bis(diethyldithiocarbamato)-stereochemistry, 60 Selenium, bis(dithiofurancarbamato)-stereochemistry, 60 Selenium(II) complexes bis(dithiochelate), 60 Selenocyanate complexes linkage isomers, 186 Selenonium ions, trifluoro-stereochemistry, 37 Self-exchange reactions, 333 electron transfer rate constants, 347-353, 366 rate constants calculation, 348 rate constants, 362 Semicarbazide, 1,4-diphenylthio-ruthenium determination, 546 Semi-glycinecresol red metallochromic indicator, 557 Semi-xylenol orange metallochromic indicator, 557 Seven-coordinate compounds stereochemistry, 69-83 Sidgwick, Nevil Vincent, 16 Silicon, tris(acetylacetone)-configuration, 195... [Pg.600]

Linkage isomerization of thiocyanate in [Pd(Et4dien)(SCN)]+ takes place more rapidly than that of selenocyanate in [Pd(Et4dien)(SeCN)]+. This observation is consistent with a dissociative mechanism, with relief of steric strain in transition-state formation, for isomerization. The activation enthalpy for the isomerization of [Pd(Et4dien)(SCN)]+ to the N-bonded thiocyanato-isomer is 19.8 kcal mol and for [Pd(Et4dien)(SeCN)]+ to the N-bonded isomer it is 21.0 kcal mol the respective activation entropies are -10 and — 5 cal deg mol L ... [Pg.160]

See other pages where Selenocyanates linkage isomers is mentioned: [Pg.221]    [Pg.221]    [Pg.1141]    [Pg.255]    [Pg.256]    [Pg.359]    [Pg.297]    [Pg.6014]    [Pg.235]    [Pg.6]   
See also in sourсe #XX -- [ Pg.186 ]



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Isomer linkage

Selenocyanate

Selenocyanate complexes linkage isomers

Selenocyanates

Selenocyanation

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