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Selenium compounds hydrolysis

Not only propargyl precursors but also acceptor-substituted 1-methyleneallyl compounds such as 67, 71 or 74 can be used to produce the target allenes by sigmatropic reactions (Scheme 7.10). After oxidation of selenium compounds 67 followed by equilibration of the resulting selenoxides 68 and selenenic esters 69, hydrolysis... [Pg.367]

Alkyl Isoquinolines. Coal tar contains small amounts of l-methylisoquinoline [1721-93-3] 3-methylisoquinoline [1125-80-0] and 1,3-dimetliylisoquinoline [1721-94-4J. The 1- and 3-methyl groups are more reactive than others in the isoquinoline nucleus and readily oxidize with selenium dioxide to form the corresponding isoquinoline aldehydes (174). These compounds can also be obtained by the hydrolysis of the dihalomethyl group. The 1- and 3-methyhsoquinolines condense with benzaldehyde in the presence of zinc chloride or acetic anhydride to produce 1- and 3-styryhsoquinolines. Radicals formed by decarboxylation of carboxyUc acids react to produce 1-aIkyhsoquinolines. [Pg.398]

This was reacted with chlorine to give the dichloropregnene compound, then with selenium dioxide to give the dichloropregnadiene compound. By hydrolysis with methanolic potassium hydroxide there was obtained the free 6a-fluoro-9a,11/3-dichloro-A -pregnadiene-16a,-17a,21-triol-3,20-dione. By treatment with acetone in the presence of perchloric acid, the 16,17-acetonide of 6a-fluoro-9a,11/3-dichloro-A -pregnadiene 16a,17a,21-triol-3,20-dione was formed. [Pg.655]

The hydrolysis, alcoholysis, and aminolysis of monoselenophosphate (294) have been reported for the first time (294) is the labile selenium donor compound required for the synthesis of Se-dependent enzymes and seleno-tRNAs, and is formed from ATP and selenide, HSe. The rate of hydrolysis of monoselenophosphate (294) is... [Pg.88]

Selenium hexafluoride, SeFg, the only clearly defined hexahalide, is formed by reaction of fluorine with molten selenium, It is more reactive than the corresponding sulfur compound, SFs, undergoing slow hydrolysis. Selenium forms tetrahalides with fluorine, chlorine, and bromine, and dihalides with chlorine and bromine. However, other halides can be found in complexes, e.g,. treatment of the pyridine complex of SeF/i in ether solution with HBr yields (py)2SeBrc Selenium tetrafluoride also forms complexes with metal fluorides, giving MSeF complexes with the alkali metals. [Pg.1465]

Scheme 2 shows Rapoport s synthesis [15]. The cinnamic acid derivative 3 prepared from m-methoxy benzaldehyde [20] was ethylated by diethyl sulfate to give ethyl cinnamate derivative 4, followed by Michael addition with ethyl cyanoacetate to afford compound 5. Compound 5 was converted to lactam 6 by the reduction of the cyano group and subsequent cyclization. Selective reduction of the lactam moiety of 6 was achieved by treatment with trimethy-loxonium fluorob orate followed by sodium borohydride reduction. Amine 8 was obtained by the reductive methylation of amine 7. Amine 8 was converted to compound 9 by methylene lactam rearrangement [21], followed by selenium dioxide oxidation to provide compound 10. Allylic rearrangement of compound 10 and subsequent hydrolysis gave compound 12. The construction of the decahydroisoquinoline structure began with compound 12,... [Pg.106]


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See also in sourсe #XX -- [ Pg.208 ]

See also in sourсe #XX -- [ Pg.208 ]




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Hydrolysis compounds

Selenium compounds

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