Selenides, acyl phenyl reductive decarboxylation

Overall reductive decarboxylation of a carboxylic acid may be achieved by the reaction of the derived acyl chloride with triisopropyisilane (equation 12). Relatively high temperatures are required to bring about efficient decarbonylation of die intermediate acyl radical. A related mediod involves the reaction of acyl phenyl selenides with tri-it-butyltin hydride. Here again relatively high temperatures are required for primary and secondary, although not for tertiary, acids (equation 13). 

---

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ ]

---