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Schrodinger equation asymptotic behavior

Equation (10.38) is recognized as the Schrodinger equation (4.13) for the one-dimensional harmonic oscillator. In order for equation (10.38) to have the same eigenfunctions and eigenvalues as equation (4.13), the function Slq) must have the same asymptotic behavior as in (4.13). As the intemuclear distance R approaches infinity, the relative distance variable q also approaches infinity and the functions F(R) and S(q) = RF(R) must approach zero in order for the nuclear wave functions to be well-behaved. As 7 —> 0, which is equivalent to q —Re, the potential U(q becomes infinitely large, so that F(R) and S(q rapidly approach zero. Thus, the function S(q) approaches zero as q -Re and as Roo. The harmonic-oscillator eigenfunctions V W decrease rapidly in value as x increases from x = 0 and approach zero as X —> oo. They have essentially vanished at the value of x corresponding to q = —Re. Consequently, the functions S(iq in equation (10.38) and V ( ) in... [Pg.275]

Determine the asymptotic behavior of the Schrodinger equation and of xj/. This produces a gaussian factor exp(-y /2) times a function of y, f y). [Pg.83]


See other pages where Schrodinger equation asymptotic behavior is mentioned: [Pg.275]    [Pg.82]    [Pg.42]    [Pg.248]    [Pg.65]    [Pg.275]    [Pg.73]    [Pg.298]    [Pg.60]    [Pg.77]    [Pg.153]   
See also in sourсe #XX -- [ Pg.74 , Pg.78 ]




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