Scanning electrochemical microscopy efficiency

Lee C, Kwak JY, Anson FC (1991) Application of scanning electrochemical microscopy to generation/ collection experiments with high collection efficiency. Anal Chem 63(14) 1501-1504. doi 10.1021/ac00014a030... 

Bonazza, H. L., and J. L. Fernandez, An efficient method for fabrication of disk-shaped scanning electrochemical microscopy probes with small glass-sheath thicknesses, J. Electroanal. Chem., Vol. 650, 2010 pp. 75-81. 

FIGURE 5.12 Kinetic parameter k as a function of the collection efficiency ( /s//x )- (A) E Cj mechanism K=k tPlD, solid line was computed from Equation 5.85, diamonds are simulated data taken from Ref. [5]. (B) EjCji mechanism k =c° k tP/aD, solid line was computed from Equation 5.88, squares are simulated data taken from Ref. [54]. (Reprinted with permission from Treichel, D.A., Mirkin, M.V., and Bard, A. J., Scanning electrochemical microscopy. 27. Application of a simplified treatment of an irreversible homogeneous reaction following electron transfer to the oxidative dimerization of 4-nitrophenolate in acetonitrile, J. Phys. Chem., 98, 5751-5757, 1994. Copyright 1994 American Chemical Society.)... 

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