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Saturation of Ion Current and Discrimination Based on Focusing Strength

3 Saturation of Ion Current and Discrimination Based ON Focusing Strength [Pg.230]

Focusing of ions in curved FAIMS (4.3.1) means a pseudopotential bottoming near the gap median. Devices using such wells to guide or trap ions (e.g., quadrupole filters or traps and electrodynamic funnels) have finite charge capacity or saturation current (/sat) the Coulomb potential scales as the charge density squared and, above some density, exceeds the well depth and expels excess ions from the device. Simulations [Pg.230]

The value of Eq also depends on the species and drops for those with more linear [Pg.231]

Properties of Ions (in Air) in Exemplary Simulations of Cylindrical FAIMS  [Pg.233]

4 Dependence oe Separation Metrics on Instrument Parameters IN Curved FAIMS [Pg.234]




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And base strength

Base saturation

Base strength

Bases, strengths of

Current discrimination

Current saturation

Focus On

Ion current

Ion focusing

Ion-based

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