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Salts lattice energy and thermochemistry

Manganese (.continued) salen complexes, 46 394-400 salts, lattice energy and thermochemistry, 22 48-51... [Pg.172]

NQR, 22 216 olefin complexes of, 4 85 in organogermanium compounds, 27 141,143 oxyfluoride, properties of, 11 29 pentacarbonyl dimets of sulfur oxydifluoride imide, 19 203-205 pentafluoride, structure, 27 102 peroxides, 6 325-326 phthalocyanine, 7 54 physical properties of, 11 18 polysulfide complexes, 31 100, 102 envelope conformation, 31 115 synthesis, 31 103-104 [Pt[15]aneS5) f, 35 75, 77 reaction with fluorinated peroxides, 16 120 salts, lattice energy and thermochemistry, 22 52-56... [Pg.259]

One final method for deriving gas-phase thermochemistry of hypervalent ions does not involve gas-phase experiments at all. It requires measuring solid-state heats of formation of ionic salts and correcting to gas-phase values using calculated lattice energies for these salts. Since the lattice energies are in the vicinity of 1000 kJ/mol, 1% accuracy on these values is necessary to derive gas-phase thermochemistry with error limits of ca. 10 kJ/mol. This accuracy has yet to be met in practice. ... [Pg.63]


See other pages where Salts lattice energy and thermochemistry is mentioned: [Pg.12]    [Pg.50]    [Pg.56]    [Pg.113]    [Pg.123]    [Pg.147]    [Pg.190]    [Pg.200]    [Pg.202]    [Pg.221]    [Pg.226]    [Pg.242]    [Pg.244]    [Pg.266]    [Pg.270]    [Pg.12]    [Pg.50]    [Pg.56]    [Pg.113]    [Pg.123]    [Pg.147]    [Pg.190]    [Pg.200]    [Pg.202]    [Pg.221]    [Pg.226]    [Pg.242]    [Pg.244]    [Pg.266]    [Pg.270]   
See also in sourсe #XX -- [ Pg.22 , Pg.25 , Pg.26 , Pg.27 , Pg.28 , Pg.29 , Pg.30 , Pg.77 , Pg.78 , Pg.79 , Pg.80 , Pg.81 ]




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