Surface elastic constants saddle-splay

The A" and K22, terms, which vanish identically in the apolar nematic and cholesteric phases, are not considered here. As discussed above, the volume integrals of the free energy terms containing the splay-bend elastic constant and the saddle-splay elastic constant K24 can be transformed into integrals over the nematic surface... 

The three (positive) elastic constants Kn (splay), K22 (twist), and K33 (bend) are associated to the three principal deformations. In the surface term, fs is the contribution of the two anchorings, k is the unit vector normal to the surface and directed outward, K13 is the splay-bend constant, and K24 is the saddle-splay constant. The two last surface terms play only for thin films the mere existence of the splay-bend constant K13 is a matter of debate. In the framework of Landau-de Gennes analysis, = K33 and the elastic... 

The strain tensor must conform to the symmetry of the liquid crystal phase, and as a result, for nonpolar, nonchiral uniaxial phases there are ten nonzero components of kij, of which four are independent ( i i, 22> A 33 and 24)- These material constants are known as torsional elastic constants for splay (k, 1), twist ( 22) bend ( 33) and saddle-splay ( 24) terms in 24 do not contribute to the free energy for configurations in which the director is constant within a plane, or parallel to a plane. The simplest torsional strains considered for liquid crystals are one dimensional, and so neglect of 24 is reasonable, but for more complex director configurations and at surfaces, k24 can contribute to the free energy [7]. In particular 24 is important for curved interfaces of liquid crystals, and so must be included in the description of lyotropic and membrane liquid crystals [8]. Evaluation of Eq. (16) making the stated assumptions, leads to [9] ... 

The effect of surface elastic constants on the nematic director configurations is of basic interest for the elastic theory of liquid crystals and plays a critical role in those device applications where the nematic is confined to a curved geometry. The saddle-splay surface elastic constant, K24, and the splay-bend surface elastic constant, K13, defied measurement for more than sixty years, since the pioneering work of Oseen, who made the first steps toward the elastic theory of liquid crystals. 

Measurements of the saddle-splay surface elastic constant, K24, and the splay-bend surface elastic constant, K13, were first introduced by Oseen [1] in 1933 from a phenomenological viewpoint, and later by Nehring and Saupe [2] from a molecular standpoint. These constants tend to be neglected in conventional elastic continuum treatments for fixed boundary conditions because they do not ent the Euler-Lagrange equation for bulk equilibrium. Experimental determination of tiie two surface elastic constants is undoubtedly a difficult task, since their effects are hard to discriminate from those of ordinary sur ce anchoring [3]. 

H e Ki, K2 and K3 correspond to the splay, twist, and bend bulk elastic constants, respectively. Further, the terms K24 and K13, known as the saddle-splay surface elastic constant and mixed splay-bend surface elastic c( istant, respectively, are called surface elastic constants because they enter EQN (3) as divergences of a volume integral, which are converted to surface integrals via Green s theorem. It should be noted that the second derivative of the K24 term in EQN (3) is apparent however, this is... 

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