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Ruthenium, chloro -, perchlorate

Christian and Roper (57) have isolated white crystals of a six-coordinate ruthenium(II) complex, fmns-RuH(C0)(p-tNC)(Ph3P)20C103 by treating the corresponding chloro complex with AgC104 in EtOH. The coordinated perchlorate can be readily displaced by CO or Ph3P. [Pg.265]

ClN402ReC2oH2o, Rhenium(V), dioxote-trakis(pyridine)-, chloride, trans-, 21 116 ClN406ReC2oH20, Rhenium(V), dioxote-trakis(pyridine)-, perchlorate, trans-, 21 117 C1P2RuC4iH35, Ruthenium(II), chloro(T)5-cy-clopentadienyl)bis(triphenylphosphine)-, 21 78 CITiCioHio, Titanium(III), chlorobis(n5-cyclo-pentadienyl)-, 21 84... [Pg.208]

The complex ion [Ru(bpy)(trpy)Cl] was first prepared as the perchlorate salt by the reaction of Ru(bpy)Cl4 with trpy in 25% aqueous ethanol, and more recently in 75% aqueous ethanol. It has also been prepared from Ru(CO)2(bpy)Cl2, trpy, and trimethylamine oxide in 2-methoxyethanol. A method in which the readily prepared RuftrpylClj complex is used as an intermediate is more convenient, and it is this new method that is described here. (2,2 -Bipyridine-A(,A( )chloro(2,2 6, 2"-terpyridine-Al,Al, N")osmium(II) chloride has been reported and is prepared from Os(bpy)Cl4" and trpy in ethylene glycol. (2,2 -Bipyridine-N,Al )chloro 2,2 6, 2"-terpyridine-Al,N, yV")osmium(II) chloride may also be prepared by the reaction of Os(trpy)Cl3 with bpy in ethylene glycol. However, the insolubility of Os(trpy)Cl3 in this solvent makes the procedure used for the ruthenium analog less desirable, and the literature method has been used without major modification. Reaction of the chloro complexes With hot... [Pg.299]

Fluoride, perchlorate, chloride, nitrite, phosphite, arsenate, nitrate, chlorate, sulphate, chromate, borofluoride, glycol-late, acetate,lactate, propionate, aceto-acetate, hydroxy-butyrate, chloro-acetate, isobutyrate and butyrate Ruthenium (ll-l). 10 phenanth- roline and ruthenium (1 l)-2,2 bi- pyridine mobile phases Ruthenium in 1 1 complexes used as ion interaction reagents Indirect spectrofluoro- metric [331]... [Pg.169]

See other pages where Ruthenium, chloro -, perchlorate is mentioned: [Pg.823]    [Pg.13]    [Pg.123]    [Pg.586]    [Pg.297]    [Pg.309]    [Pg.552]    [Pg.383]    [Pg.383]    [Pg.411]   
See also in sourсe #XX -- [ Pg.32 , Pg.191 ]



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Ruthenium -chloro

Ruthenium perchlorate

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