Ruthenate properties

Groessl M, Reisner E, Hartinger CG, Eichinger R, Semenova O, Timerbaev AR, Jakupec MA, Arion VB, Keppler BK (2007) Structure-activity relationships for NAMI-A-type complexes (HL)[trans-RuC14L(S-dmso)ruthenate(in)] (L = imidazole, indazole, 1, 2, 4-triazole, 4-amino-1, 2, 4-triazole, and 1-methyl-l, 2, 4-triazole) aquation, redox properties, protein binding, and antiproliferative activity. J Med Chem 50 2185-2193... 

Bae, J.M. and Steele, B.C.H., Properties of pyrochlore ruthenate cathodes for intermediate temperature solid oxide fuel cells. Journal of Electroceramics, 1999, 3, 37-46. 

P. C. Ford Coord. Chem. Rev. 5, 75 (1970) Properties and reactions of ruthen-ium(II) amine complexes 25 (67) Includes nitrogen complexes... 

Electro-Organic Oxidation Properties. Table I lists some results for the electro-oxidation of primary alcohols and propylene on leadsubstituted lead ruthenate. Propylene was cleaved with nearly 100% selectivity to acetic acid and CO2. In borate buffer at pH 9 the oxidation of propylene also occurred, and the selectivity to acetate and CO2, based on the amount of carbonate isolated, was also close to 100%. Dissolved ethanol and propanol were both converted with high selectivity to the corresponding carboxylic acid salts in alkaline electrolyte. In contrast, Pt black (also shown in Table I) oxidized ethanol to CO2 and then rapidly deactivated. 

Ruthenation appears to occur without perturbing the structure of the protein, except for perhaps local changes in the vicinity of the modified histidine. The electrochemical properties of the protein are only slightly altered by m-thenation. The E° value for the intrinsic redox cofactor of a protein typically increases by about 20 mV, consistent with the addition of a positively charged group to the protein. 

Catalytic Properties of Strontium Ruthenate Perovskite Prepared by Hot Isostatic Pressure Method... 

In the last years there has been an increase interest for the studies of supramolecular properties of tetra-ruthenated porphyrins (M-TRP), especially after the discovery of the exceptional electrocatalytic efficiency of the penta-aminomthenium-cobalt porphyrin species in the four electron reduction of... 

Fukuda K, Saida T, Sato J, Yonezawa M, Takasu Y, Sugimoto W (2010) Synthesis of nanosheet crystallites of ruthenate with an alpha-NaFe02-related structiffe and its electrochemical supercapacitor property. Inorg Chem 49 4391-4393... 

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