Ruthenate phosphorus

Si3NO,DPiRu1CsaHMI, Ruthenate(l -), deca-carbonyl-lK C,2K C,3KJC-(x-hydrido-l 2K2//-bis(triethylsilyl)-lK5i,2KS/-trion-gu(o-tri-p-nitrido-bis(triphenyl-phosphorus)-(l +), 26 269 SmOC H2, Samarium(III), tris(rf-cyclo-pentadienyl)(tetrahydrofuran)-, 26 21... 

Ruthenate(2 -), pj-carbido-tetradecacar-bonylpenta-, bis[p-nitrido-bis(triphenyl-phosphorus)( I +)), 26 284... 

RU2CL4C24H36, Ruthenium(II), di-p-chloro-bis[chloro(i)6-hexamethylbenzene)-, 21 75 RU3C0NO13P2C49H30, Ruthenale(l -), trideca-carbonylcobalttri-, p.-nitrido-bis(triphenyl-phosphorus)(l +), 21 63 Ru3FeNO 13P2C49H31, Ruthenate(l —), trideca-carbonyIhydridoirontri-, p.-nitrido-bis(triphenylphosphorus)(l + ), 21 60 Ru3FeOi3Ci3H2, Iron,... 

N2C])H24, 1,2-Ethanediamine, N,N-bis-(1-phenyiethyl)-, S,S) platinum complex, 21 87 N2C2i)H2g, 1,2-Ethanediamine, N,Af -dimethyl-/V, -bis(l-phenylethyl)-, (/ ,/ )-, platinum complex, 21 87 NjOgCgHio, 1,2-Cyclohexanedione, dioxime boron-iron complex, 21 112 N2O2P2C34H30, Phosphorus 1-H), n-nitrido-bis(triphenyl-, nitrite, 22 164 N20 P2Ru3C4 H3o, Ruthenate(l-), decacar-bonyl-p.-nitrosyl-tri-, p,-nitrido-bis(triphenylphosphorus) (1 +), 22 163, 165... 

Two out of the three products of base hydrolysis of the [Co(NH3)5(p-nitrophenylphosphate)] cation arise from attack of hydroxide at the coordinated ligand. These products are p-nitrophenolate and hydroxophosphor-amidotetraamminecobalt(Ill). These result from intramolecular attack at the phosphorus by a deprotonated coordinated ammine ligand, which generates a five-coordinate aminophosphorane. Ester hydrolysis is about 10 times faster in this complex than in the free / -nitrophenylphosphate—one of the most dramatic examples of the kinetic consequences of coordination to a metal center, comparable with the activation of acetonitrile on coordination to ruthen-... 

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