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Rubber elasticity single molecule

VII. Enthalpic and Entropic Contributions to Rubber Elasticity Force-Temperature Relations Vtn. Direct Determination of Molecular Dimensions IX. Single-Molecule Elasticity References... [Pg.157]

Hanson, D. E. Martin, R. L., How Ear Can a Rubber Molecule Stretch Before Breaking Ah Initio Study of Tensile Elasticity and Failure in Single-Molecule Polyisoprene and Polybutadiene. J. Chem. Phys. 2009,130, 064903. [Pg.80]

The statistical mechanical theory for rubber elasticity was first qualitatively formulated by Werner Kuhn, Eugene Guth and Herman Mark. The entropy-driven elasticity was explained on the basis of conformational states. The initial theory dealt only with single molecules, but later development by these pioneers and by other scientists formulated the theory also for polymer networks. The first stress—strain equation based on statistical mechanics was formulated by Eugene Guth and Hubert James in 1941. [Pg.16]


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