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Ring opening polymerization aliphatic polyesters

Mecerreyes, A, Dubois, P and Jerdme, R. Novel Macromolecular Architectures Based on Aliphatic Polyesters Relevance of the Coordination-Insertion Ring-Opening Polymerization. VoL 147, pp. 1 -60. [Pg.212]

Aliphatic polyesters occupy a key position in the field of polymer science because they exhibit the remarkable properties of biodegradability and biocompatibihty, which opens up a wide range of applications as environmentally friendly thermoplastics and biomaterials. Three different mechanisms of polymerization can be implemented to synthesize aliphatic polyesters (1) the ring-opening polymerization (ROP) of cyclic ketene acetals, (2) the step-growth polymerization of lactones, and (3) the ROP of lactones (Fig. 1). [Pg.174]

Coulembier O, Degee Ph, Hedrick JL, Dubois Ph (2006) From controlled ring-opening polymerization to biodegradable aliphatic polyester especially poly(P-malic acid) derivatives. Prog Polym Sci 31 723-747... [Pg.209]

Trollsas M, Lee VY, Mecerreyes D, Ldwenhiehn P, Moller M, Miller RD, Hedrick JL (2000) Hydrophilic aliphatic polyesters design, synthesis, and ring-opening polymerization of functional cyclic esters. Macromolecules 33 4619-4627... [Pg.214]

Detrembleur C, Mazza M, Halleux O, Lecomte P, Mecerreyes D, Hedrick JL, Jerome R (2000) Ring-opening polymerization of y-Bromo-E-caprolactone a novel route to functionalized aliphatic polyesters. Macromolecules 33 14-18... [Pg.214]

El Habnouni HS, Darcos V, Coudane J (2009) Synthesis and ring-opening polymerization of a new functional lactone, a-iodo- -caprolactone a novel route to functionalized aliphatic polyesters. Macromol Rapid Commun 30 165-169... [Pg.214]

Tian D, Dubois P, Grandfils C, Jerome R (1997) Ring-opening polymerization of l,4,8-trioxaspiro[4.6]-9-undecanone A new route to aliphatic polyesters bearing functional pendent groups. Macromolecules 30 406 09... [Pg.215]

Scheme 1 a Ring-opening polymerization of cyclic esters in the presence of SnOct2 and hydroxo-initiator, and b its application to the synthesis of polysaccharide-gra/t-aliphatic polyesters (or poly(hydroxyalkanoate)s)... [Pg.103]

Another approach, which does not make use of either free or controlled radical polymerization, was demonstrated by Parrish et al. [20]. An aliphatic polyester with pendent acetylene groups was prepared via controlled ring-opening polymerization. Polyethylene glycol and the peptide sequence Gly - Arg - Gly - Asp - Ser (GRGDS) were functionalized with an azide moiety, and subsequently clicked to the pendent acetylenes in the... [Pg.22]

See other pages where Ring opening polymerization aliphatic polyesters is mentioned: [Pg.18]    [Pg.31]    [Pg.85]    [Pg.28]    [Pg.71]    [Pg.209]    [Pg.111]    [Pg.3]    [Pg.90]    [Pg.173]    [Pg.153]    [Pg.278]    [Pg.3]    [Pg.91]    [Pg.139]    [Pg.10]    [Pg.344]    [Pg.27]    [Pg.23]   
See also in sourсe #XX -- [ Pg.249 , Pg.251 ]



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