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Rigid pendant groups, effect

TABLE 4.5. Effect of Rigid Pendant Groups on Jg in (CHj-CHX) Polymers... [Pg.344]

Intermolecular relaxation effects are a central issue in the interpretation of the ultraviolet photoelectron spectroscopy (UPS) of molecular solids. These relaxation effects result in several significant characteristics of UPS valence spectra, intermolecular relaxation phenomena lead to localized electron molecular-ion states, which are responsible for rigid gas-to-solid molecular spectral energy shifts, spectral line broadening, and dynamic electronic localization effects in aromatic pendant group polymers. [Pg.145]

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Pendant Group Effects

Pendant group

Rigid groups