Ridil s chemical mechanisms of the catalytic reaction

In the simplest variant it is proposed that the presented reaction is realized via the totality of an elementary reaction 

Let us complicate scheme (2.30) by introducing a possible elementary reaction, but by own stoichiometry. 

An elementary reaction ((l)-(3) in scheme (2.30)) and a reaction (4) in scheme (2.31) represent a so-called sequential redox mechanism, that is, oxidization-reduction of a catalyst by one of the components of reactive mixture, whereas elementary reactions (5) and (6) in equation (2.31) represent a so-called associated mechani.sm in which two 

All of these realize a final reaction in the stoichiometric form (2.29), that is why (5/= 1. Furthermore, we have another two routes formed by a cyclic sequence of the three elementary reactions (the first of them is already known)  

Route Ui yields a final reaction in the stoichiometric form 4CO + 2O2 — 4CO2, that is why the stoichiometric number of the final reaction (2.29) is equal to 2. Subsequently, the rate of the reaction (2.29) is equal to 

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