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Rhodium complexes isocyanide

If RhCl3 SHjO and methyl isocyanide are reacted under mild conditions, and then 1 added, the rhodium(III) isocyanide complex Rh(CNCH3)3l3 is obtained (11). [Pg.65]

Tab. 11.9 Rhodium complex-catalyzed coupling of various diynes with isocyanide. Tab. 11.9 Rhodium complex-catalyzed coupling of various diynes with isocyanide.
NOCkH, Benzoyl isocyanide, chromium complex, 26 32, 34, 35 NOPC25H21, Benzamide, 2-(diphenylphos-phino)-lV-phenyl-, 27 324 NOPC22H22, Benzamide, iV-(2-(diphenyl-phosphino)phenyl]-, 27 323 NO2QH5, 4-Pyridinecarboxylic acid, rhodium complex, 27 292... [Pg.398]

Table 2 Polymerization of aryl isocyanides 28a-c catalyzed by rhodium complexes 27... Table 2 Polymerization of aryl isocyanides 28a-c catalyzed by rhodium complexes 27...
A method for the stabilization of the isocyano metabolites by formation of rhodium complexes has been developed. The (r 5-pentamethylcyclopentadienyl)- or (r 5-ethyltetramethylcyclopenta-dienyl)-di- i-thiocyanato rhodium complexes of the isocyanides (eg 129) normally provide stable, crystalline compounds, thus facilitating the analysis and the purification of these metabolites [139,140]. [Pg.222]

NOCgHj, Benzoyl isocyanide, chromium complex, 26 32,34,35 N0C,3H,3, Formanide, N-(l-(l-naphthal-enyl)ethyll-, rhenium complex, 29 217 NOPCjsHjj, Benzamide. 2-(diphenylphos-phino)-N-phenyl-, 27 324 NOPCjjHjj, Benzamide, Af-[2-(diphenyl-phosphino)phenyl]-, 27 323 NO2CH3, Methane, nitro-, antimony complex, 29 113 cobalt complex, 29 114 NOjCjHj, 4-Pyridinecarboxylic acid, rhodium complex, 27 292 NO2P2C3JH33, Phosphorus(l-t-), p-nitrido-bis(triphenyl-, acetate, 27 296 NO2SC3H7, L-Cysteine, molybdenum complex, 29 255,258... [Pg.378]

Further Studies of the Spectroscopic Properties and Photochemistry of Binuclear Rhodium(I) Isocyanide Complexes... [Pg.225]

CjHgOs, Butanoic acid, 3-oxo-, methyl ester, rhodium complex, 27 292 C,H,N, tert-Butyl isocyanide, chromium, molybdenum, and tungsten complexes, 28 143... [Pg.393]

Rice, S. F. Milder, S. J. Gray, H. B. Goldbeck, R. A. Kliger, D. S. Photophysical Properties of the lowest Electronic Excited States of Binuclear Rhodium(I) Isocyanide Complexes, Coord. Chem. Rm. 1982,45,349... [Pg.160]

Lithium or potassium indenyl has been used to generate both iridium complexes and isocyanide rhodium complexes of the form (n indenyl)Rh(CNR)2. Bimetallic complexes of Co,Rh and Ir have been made using thallium fulvanate Tl2(CioH8)- With the linked permethylcyclopentadienyl lithium reagent dirhodium complexes such as (19) can be made. ... [Pg.358]

Square-planar rhodium(I) isocyanide complexes [Rh(RNC)4]" re prone to oligomerization in acetonitrile solution. Oxidations of the monomeric form by a series of [Fe(phen)3] and [Fe(bipy)3] derivatives... [Pg.52]

See other pages where Rhodium complexes isocyanide is mentioned: [Pg.181]    [Pg.151]    [Pg.180]    [Pg.181]    [Pg.211]    [Pg.1738]    [Pg.4102]    [Pg.5422]    [Pg.44]    [Pg.74]    [Pg.4101]    [Pg.5421]    [Pg.349]    [Pg.418]    [Pg.621]    [Pg.1738]    [Pg.113]    [Pg.307]    [Pg.45]    [Pg.66]    [Pg.424]    [Pg.221]    [Pg.266]    [Pg.180]    [Pg.199]   
See also in sourсe #XX -- [ Pg.625 , Pg.627 , Pg.628 ]



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Dimeric rhodium isocyanide complexes

Isocyanide complexes

Isocyanides complexes

Rhodium isocyanides

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