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Rhodium complexes alkylphosphine ligands

Yoshida and Otsuka found that platinum(O) complexes [PtLj] (26) (a L = PEtj b L = P Prj) and rhodium hydrido complexes such as [RhHLj] (L = P Prs 33, PEts), [RhiHidr-NJlPCyslJ (34), tram-[RhH(N2)(PPh Bu2)J, and [RhH(P Bu3)J, all of which carry electron-donating alkylphosphine ligands, can catalyze the water gas shift reaction under fairly mild conditions (100-150°C CO 20 kg/cm ) (Eq. 6.32) [23, 60]. Among these complexes, [RhH(P Pr3)3] (33) was the most active catalyst precursor. Several complexes were isolated from or detected in the reaction mixture... [Pg.193]

See other pages where Rhodium complexes alkylphosphine ligands is mentioned: [Pg.380]    [Pg.1078]    [Pg.23]    [Pg.588]    [Pg.592]    [Pg.76]    [Pg.430]    [Pg.26]    [Pg.199]    [Pg.262]    [Pg.276]    [Pg.656]    [Pg.252]   
See also in sourсe #XX -- [ Pg.7 ]



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