Rhodium, chloro trans

CX lPjRhCjjHjo, Rhodium, carbonylchloro-bis(tiiphenylphosphine)-, trans-, 28 79 OClP]RhS2C42H] Rhodium, chloro[[2-[(diphenylphosphino)methyl]-2-methyl-l,3-propanediyl]bis(diphenyl-phosphine)](dithiocarbonatoK 27 289 OCI4M0, Molybdenum tetrachloride oxide, 28 325... 

Nitrosylpentaamminecobalt(II) chloride, synthesis 49 cts-Bromoamminebis (ethylenediamine) cobal t (111) bromide, CIS- and trans-aquoamminebis(ethylenediamine)cobalt(IIl) bromide, and cis- and triphenylphosphine)rhodium and chloro-carbonylbis(triphenylarsine)rhodium, synthesis 56 Sodium hexachlororhodate(III) 2-hydrate and potassium hexachlororhodate(III) 1-hydrate, synthesis 57 Ammonium hexachloroiridate(IV), synthesis 58 Resolution of the tris(l,10-phenanthroline)nickel(II) ion, synthesis 59... 

CIFgIrN406S2CgHi6, Iridium(III), chloro-bis(l, 2-ethanediamine)(trifluoro-methanesuIfonato-O)-, trans-, trifluoro-methanesulfonate, 24 289 ClFgN406RhS2C6H,6, Rhodium(III), chloro-bis(l,2-ethanediamine)(trifluorometh-anesulfonato-0)-, trans-, trifluorometh-anesulfonate, 24 285... 

The present preparative procedure for perchlorato complexes of rhodium and iridium appears to be of general utility for the synthesis of perchlorato complexes of transition metals. The assignment of trans planar structures for [M(OC103)(CO)(Ph3P)2] (M = Ir, Rh) is based on the vibrational and electronic spectral similarities between the perchlorato complexes and their well-known chloro precursors, tims-[MCl(CO)(Ph3P)2].5,6... 

Z>) Reactions of [Rh(NH ),X. The aquation and anation of [Rh(NH3X]" in acidic aqueous solution (equation 105 was first studied by Lamb who used conductance changes to monitor the interconversion of acido and aqua rhodium complexes , for the chloro and bromopentaanimine-rhodium(III) cations. He found that both aquation and anation are first-order in [Rh ], and that the hydrolysis is accelerated by the presence of OH . The forward form of equation (105) (aquation) has since been studied for X = Cl-, Br , l-, >.=56 oHj, SO, NO3" and Nj . Representative results for the aquation of various pentaammine salts are given in Table 25. For aquations of halides or nitrate ions, rate expressions which are first-order in [Rh] and zero-order in [H+] are found. Poe gives a detailed discussion of the thermodynamic, kinetic and intrinsic-kinetic trans effects, and compares the aquation and anation of [Rh(NH3)5X]-" (X = Cl, Br and I) with the [RhfenjjXY]" system. When X = S04, a two-term rate expression was observed... 

Figure 18.3 Structure of trans-chloro(dinitrogen)-, chloro(dioxygen)-, and chloro-(ethylene)-bis(tri-isopropylphosphine[rhodium [39],...

C3 7H2 5Fe205PS, Dicarbonyl (triphenyIphosphine) iron-/Li (1,2-diphenyl-ethylene-1 -thiolato-2-yl)-tricarbonyl iron, 44B, 727 C37H3oC10P2Rh, trans-Carbonyl-chloro-bis(triphenylphosphine)rhodium-(I), 45B, 894... 

Cl bHi,2ClN2P2Rh, trans-Chloro(dinitrogen)bis(tri-isopropyIphosphine)-rhodium(I), 43B, 1043 45B, 1339... 

C3 1H22AS2Cl206Re2 0,25 CsHu, /ii-Bis(diphenylarsino)methane-hexa-carbonyldi-/x chloro-dirhenium(I) n-hexane, 41B, 1193 C31H24ClN60P2Rh, trans-Carbonylchlorobis(tris(2-pyridylphosphine))-rhodium, 46B, 1275... 

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