Rhodium-Catalyzed Vinyldiazoesters Insertion Into Si—H Bonds. Synthesis of Allylsilanes

University of Bordeaux, Institute of Molecular Sciences, Talence, France 

The reaction proceeds as a titration with the yellow-orange coloration of diazoesters rapidly vanishing upon consumption 

Efficient Methods for Preparing Silicon Compounds. ht //dx.doLoi l0.1016/B978-0-12-803530-6.00002-0 

A dry 100-mL three-necked flask equipped with a magnetic stirrer, an inlet for argon, a thermometer, safety glasses, laboratory coat, and protective gloves. 

To a stirred solution of methyl (Z)-2-diazonon-3-enoate (451 mg, 2.3 mmol) and dimethylphenylsilane (626 mg, 4.6 mmol) in dry 

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RHODIUM-CATALYZED VINYLDIAZOESTERS INSERTION INTO Si-H BONDS. SYNTHESIS OF ALLYLSILANES... 

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