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Hydrido complexes rhenium

Hydrido complexes of rhenium synthesis and reactivity, D. Giusto, Inorg. Chim. Acta, Rev., 1972, 6,91-101(61). [Pg.65]

Another synthetic approach to the octahedral complexes of type (252) is provided by the thermal decomposition of the hydrido complex [ReH7(PPh3)2] in the presence of 2-mercapto-quinoline or 2-hydroxyquinoline in 1,2-dichloroethane solutions. The solvent is source of the chloro ligands and, thus, essential for the formation of the rhenium(III) products. Comparable reactions in THF afford hydridorhenium(V) complexes (see Section 5.3.2.11). [Pg.347]

Table 6 Some Mononuclear Hydrido Complexes of Rhenium(III) and Their Spectroscopic Properties... [Pg.151]

A model reaction related to step C in Scheme 2 is the photochemically induced [1,2] migratory insertion of metal bonded aryl groups to a metal 0x0 group in hydrido trispy-razolylborato rhenium(V) complexes. [16]... [Pg.136]


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See also in sourсe #XX -- [ Pg.995 ]

See also in sourсe #XX -- [ Pg.254 , Pg.668 ]




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Hydrido complex

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