Rhenium complexes perchlorates

In 1986, Breikss and Abruna reported electrochemical and mechanistic studies on a close analogue of the rhenium complex, (Dmbpy)Re[CO]3Cl, where Dmbpy = 4,4 dimethyl 2,2 bipyridine. The cyclic voltammogram of the complex at platinum in CH3CN/tetrabutylammonium perchlorate is shown in Figure 3.56 for simplicity we will consider only the electrochemistry taking place above c. —2.3V vs. SCE. 

The formation of micelles with different shapes was also observed in PS- -P4VP coordinated with rhenium complex. Micelles with interesting shapes were prepared from rhenium-containing block copolymer by the reaction between Re(bpy)(CO)3Cl with various PS-Z -P4VP in the presence of silver perchlorate (Scheme 5.4).69,70 Instead of converting the metal salt into... 

The six-coordinate Re(C0)3(bipy)0C103 and Re(C0)50C103 are probably the only perchlorate complexes that are known for rhenium. They are prepared by treating the respective bromides with AgC104 in di-chloromethane (54). 

Oxo transfer reactions of perchlorate and other substrates catalyzed by rhenium oxazoline and thiazoline complexes 03CC2102. 

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