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Rhenium catalysts olefin epoxidation

Since 1989 organorhenium(VII) oxides, especially the very stable methyltrioxo-rhenium (MTO), have proven to be excellent catalyst precursors for a surprisingly broad variety of processes, among them various oxidation reactions [1-3], This section gives a brief summary of the behavior of MTO and its peroxo derivatives in aqueous multiphase systems. Particular emphasis is given to the well-examined olefin epoxidation reactions. [Pg.210]

R. Saladino, V. Neri, A. R. Pelhccia, R. Caminiti, C. Sadun, Preparation and structural characterization of polymer-supported methyl rhenium trioxide systems as efficient and selective catalysts for the epoxidation of olefins, J. Org. Chem. 67, 1323-1332 (2002). [Pg.211]


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Catalysts epoxidation

Epoxides catalyst

Olefinic epoxides

Olefins epoxides

Olefins, epoxidation

Rhenium catalysts

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