Resonance states normalization

The SQ method extracts resonance states for the J = 25 dynamics by using the centrifugally-shifted Hamiltonian. In Fig. 20, the SQ wavefunc-tion for a trapped state at Ec = 1.2 eV is shown. The wavefunction has been sliced perpendicular to the minimum energy path and is plotted in the symmetric stretch and bend normal mode coordinates. As anticipated, the wavefunction shows a combination of one quanta of symmetric stretch excitation and two quanta of bend excitation. The extracted state is barrier state (or quantum bottleneck state) and not a Feshbach resonance. 

Excimer may relax (i) by emission of characteristic structureless band shifted to about 6000 cm-1 to the red of the normal fluorescence, (ii) dissociate nonradiatively into original molecules, (iii) form a photodimer. Those systems which give rise to photodimers may not decay by excimer emission. The binoing energy for excimer formation is provided by interaction between charge transfer (CT) state A+A- A-A and charge resonance state AA s A A. 

Normally, a narrow resonance is coupled with the dense set of background resonance states. Because the background states look alike, the coupling between the narrow state and the background is not specific and the variation of a parameter, for example J, does not appreciably change... 

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